TheArkOfTurus posted...1. Fallout: New Vegas
2. Deus Ex: Human Revolution
3. Fallout 3
4. Bioshock
5. Call of Duty 4
6. Borderlands
Not that big on multiplayer shooters, and I don't have a PS3/Gaming quality PC, so my list is pretty limited. There's some other stuff that I enjoyed a little bit, but not really enough to put on a list (Battlefield 3, Fear.)
I definitely wouldn't call FO3/NV or Deus Ex FPS' (Borderlands is kind of iffy too but I guess I can see it). Unless we're using the barebones definition of FPS.
Anyway, TF2 and HL2+Episodes are great answers here.
Fallout/NV I'll give you, maybe Deus Ex(there are other options besides shooting, but strictly going that route opens up so many problems in what is and isn't considered an FPS) but Borderlands is absolutely one, or at the least an FPS/RPG hybrid.
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Joyrock
Fresh from my first justified ban. Ever!