I did some tweaking to brands and pushes and such, leaving us with this. Faces are bold, heels are italics.
RAW
MAIN EVENT
John Cena
Alberto Del Rio (WWE Champion)
CM Punk
UPPER MIDCARD
Alex Riley
John Morrison
Kofi Kingston (Unified Tag Champion)
Dolph ZIggler (US Champion)
Jack Swagger
Kevin Nash
MIDCARD
Evan Bourne (Unified Tag Champion)
Justin Gabriel
Mason Ryan
David Otunga
Drew McIntyre
Heath Slater
JTG
LOWER MIDCARD
Michael McGillicutty
Tyler Reks
Primo
OPENERS
Titus O'Neil
Curt Hawkins
JOBBER
Johnny Curtis
WOMEN
Eve
Kelly Kelly (Divas' Champion)
Beth Phoenix
Brie Bella
Maryse
Maxine
Nikki Bella
Managers: Ricardo Rodriguez, Stephanie McMahon, Vickie Guerrero
Announce Team: JR/Cole/King
GM: Triple H
Other: Scott Stanford
SMACKDOWN
(A couple of odd assignments that I plan to explain)
MAIN EVENT
Randy Orton
Sheamus
Mark Henry (World Champion)
R-Truth
The Miz
Wade Barrett
UPPER MIDCARD
Zack Ryder
Christian
Cody Rhodes (IC Champion)
MIDCARD
Daniel Bryan (Money in the Bank)
Ezekiel Jackson
Sin Cara
Brodus Clay
Sin Cara II
Ted Dibiase
Tyson Kidd
LOWER MIDCARD
Percy Watson
Yoshi Tatsu
Darren Young
Jinder Mahal
OPENERS
Jey Uso
Jimmy Uso
Derrick Bateman
JOBBER
Trent Barreta
WOMEN
AJ
Alicia Fox
Kaitlyn
Aksana
Natalya
Rosa Mendes
Tamina
Occasional Wrestler: The Undertaker
Manager: Hornswoggle
Announce Team: Matthews/Book/Striker
GM: Teddy Long
Other: John Laurinitis, ???, Carlos Cabrera, Hugo Savinovich
Managers:
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Currently playing: TEW '10, Pokemon Black, Gemcraft Labyrinth, Sharin no kumi, BlAcK TuRtLe